Disclaimer: all dates are approximate, as my memory isn't what it used to be...
I think the first specs for PGU/12-B were written in the mid-70s, and I know it was already being issued at my first base of assignment when I got there in 1980. M41 ball was phased-out within a year or two, but was re-issued in limited quantities in the mid-80s for use in AFOSI (Air Force Office of Special Investigations) 5-shot .38 revolvers (S&W model 36). Testing by AFOSI HQ showed the PGU would beat the little J-frames to an early death, so for the remaining time they were used, they were filled (training
and qualification) with M41 ball.
Changeover dates in items like duty ammo were usually done with instructions reading something like "Beginning on date ##-XXX-####...", and ending with "...to be completed NLT date ##-XXX-####" (NLT = Not Later Than). For this reason, while you can probably find out which units got "issued" the ammo first (delivered to their ammo storage point or armory), that might not have much bearing on which units got it into the hands of the end-user first. Smaller bases with fewer users would probably field it very quickly; large bases with hundreds of users might take longer to get everything swapped-over.
Here is a visual comparison of the two rounds (click to enlarge):
The radical deep-seating of the bullet made it very easy to visually ID the PGU-12/B load. I think it was the same bullet (definitely the same weight, 130 grains) as the M41, they just seated it much deeper and applied a cannelure to the case to force it into the bullet's crimping groove, THEN they crimped the mouth of the case over the bullet's ogive. It was definitely hotter-loaded than the old M41 and the WW 148 factory wadcutter loads we formerly used for training. Although I've also read that Lake City made PGU-12/B ammo, the above rounds were both produced by Winchester (WCC headstamp), with the M41 showing a 72 year on the headstamp, and the PGU-12/B showing 89.
We still used the WW wadcutter loads for training for several years until it ran out; eventually, we switched-over to training with the PGU-12/B load for all users of model 15s and 56s (with M41 ammo for AFOSI agents in their model 36s). There was much sniveling when the changeover occurred; the wadcutters were VERY accurate and mild, and the PGU turned the model 15s into raging beasts (according to the older cops). :supergrin: